
NPK Bulk Cargo Logistics: Stowage and Compatibility demands precise classification under the IMSBC Code because the line between a routine Group C voyage and a high-risk Group B shipment rests on a single trough test result and the ammonium nitrate threshold. Misclassification triggers port state detention, costly re-stowage, and voided insurance, while correct paperwork unlocks the right ventilation regime, segregation rules, and gas monitoring plan for the entire voyage.
This guide covers the regulatory boundary between IMSBC and IMDG codes, the physical properties that drive hold capacity and trimming decisions, the chemical hazards unique to ammonium nitrate blends, and the moisture dynamics that dictate ventilation strategy. You will learn how to read a shipper's declaration, apply the compatibility matrix for mixed-grade parcels, and satisfy charterparty cleanliness standards so the cargo loads clean, sails safe, and discharges without claim.
NPK fertilizers fall under IMSBC Code Group B when they contain ammonium nitrate in concentrations that create a fire or explosion hazard, typically above 70 percent ammonium nitrate with added combustible material, or when the blend meets the criteria for MHB (Materials Hazardous Only in Bulk) classification due to self-sustaining decomposition risk. Group C applies to NPK formulations that present no significant fire, explosion, or toxic gas evolution hazard during transport, generally those with ammonium nitrate content below the Group B threshold and no added fuel sensitizers. The shipper's declaration and the manufacturer's certificate must confirm the correct group assignment before loading begins. Global fertilizer trade volumes reached 185 million tonnes in 2025, a 3 percent increase over 2024, according to FAO (via Agro Spectrum India), underscoring the volume of cargo requiring precise classification.
UN 2067 applies to ammonium nitrate based fertilizers of Group B that are classified as oxidizing substances under Class 5.1, requiring the proper shipping name "Ammonium nitrate based fertilizer" and compliance with IMDG Code provisions for packaged goods if not shipped in bulk under IMSBC special provisions. UN 2071 covers ammonium nitrate based fertilizers of Group C that are not classified as dangerous goods under IMDG but remain subject to IMSBC Code requirements for bulk transport, using the shipping name "Ammonium nitrate based fertilizer, non-hazardous." The distinction hinges on the outcome of the trough test and detonation test prescribed in the IMSBC Code appendix; a pass moves the cargo to Group C and UN 2071, while a fail retains Group B and UN 2067 status.
Bulk shipments of NPK fertilizer are governed primarily by the IMSBC Code, which sets stowage, ventilation, and monitoring standards for solid bulk cargoes. The IMDG Code applies only when NPK is transported in packaged form, such as bulk bags or IBCs, or when a Group B cargo requires the additional segregation and documentation rules of Class 5.1. A vessel carrying NPK in bulk follows the IMSBC schedule for the assigned group, while the same cargo in 500 kg bulk bags would require a dangerous goods manifest, container packing certificate, and IMDG segregation tables. Charterparties must specify which code governs to avoid disputes over hold preparation standards and liability for misdeclaration.
| Parameter | IMSBC Group B (UN 2067) | IMSBC Group C (UN 2071) |
|---|---|---|
| Primary Hazard | Fire and explosion risk (oxidizer) | No significant hazard in bulk |
| Ammonium Nitrate Content | Typically >70% with combustible material | Below Group B threshold |
| Trough Test Result | Fail (propagation of decomposition) | Pass (no propagation) |
| IMDG Code Applicability | Applies if packaged | Not applicable |
| Ventilation Requirement | Mechanical ventilation mandatory | Natural ventilation usually sufficient |
| Gas Monitoring | Continuous O2 and toxic gas | Periodic checks |
The table contrasts the operational impact of Group B versus Group C classification. Group B cargoes demand mechanical ventilation, continuous gas monitoring, and strict segregation from fuel sources, increasing voyage operating costs. Group C cargoes allow simpler hold management but still require moisture control and temperature profiling. Correct classification at the loading port avoids costly re-stowage or port state detention at discharge.
The stowage factor of NPK fertilizer typically ranges from 0.95 to 1.15 cubic metres per tonne depending on granule size, moisture content, and formulation density. A standard 15-15-15 grade often stows at 1.05 m³/t, while high-nitrogen blends with dense ammonium nitrate prills can reach 0.95 m³/t. Accurate stowage factor data from the shipper's certificate allows the chief officer to calculate the maximum cargo tonnage per hold without exceeding the vessel's cubic capacity or permissible load density. Global fertilizer trade value surged to approximately $81 billion in 2025, compared with $68 billion in 2024, according to FAO (via Agro Spectrum India), reflecting the high value of cargo space optimization.
The angle of repose for NPK bulk cargo generally falls between 30 and 38 degrees, varying with particle size distribution and moisture level. Fines-rich blends tend toward the lower end, increasing flowability and shift risk, while coarse granular grades maintain steeper cones. IMSBC Code requires trimming to reduce the peak height and create a level surface when the angle of repose exceeds 35 degrees or when the cargo is loaded in partially filled holds. Trimming is typically achieved by alternating pours across the hold width or using a bulldozer to flatten the surface, ensuring the cargo surface remains within the stability criteria for the voyage.
Bulk density for NPK fertilizers varies from 950 kg/m³ for lightweight prilled blends to 1,150 kg/m³ for compacted granular grades. High-phosphorus formulations containing dense monoammonium phosphate push density toward the upper range, while high-potassium blends with coarse potassium chloride settle near 1,050 kg/m³. This variance directly affects the weight loaded per cubic metre and the resulting deck load on hatch covers and tank tops. Load planners must use the specific bulk density declared by the manufacturer rather than a generic average to avoid overstressing the ship structure.
| NPK Grade Type | Typical Stowage Factor (m³/t) | Bulk Density (kg/m³) | Angle of Repose (degrees) | Trimming Required |
|---|---|---|---|---|
| Standard 15-15-15 granular | 1.05 | 1,050 | 34 | Yes if hold partly filled |
| High Nitrogen (27-0-0 blend) | 0.95 | 1,150 | 32 | Yes |
| High Phosphorus (10-26-26) | 1.00 | 1,100 | 36 | Yes |
| High Potassium (12-12-17) | 1.10 | 1,000 | 35 | Yes |
| Prilled blend (fines rich) | 1.15 | 950 | 30 | Yes |
The table summarizes how formulation chemistry drives physical handling parameters. High-nitrogen dense blends maximize weight per hold but reduce cubic utilization, while prilled fines-rich cargoes demand aggressive trimming due to low angle of repose. Operators use these figures to select the optimal vessel size and to prepare the loading sequence that satisfies both stability and hatch cover load limits.
Ammonium nitrate content thresholds and detonation triggers define the safety classification of NPK blends under the IMSBC Code. Fertilizers containing more than 28 percent ammonium nitrate by mass fall into Group B and require a certificate from the competent authority of the country of origin confirming resistance to detonation. The primary detonation triggers are confinement, strong heating, and contamination with combustible materials such as fuel oil, sawdust, or organic impurities. Global fertilizer consumption rose by less than 1.0 percent to 209 million tonnes in 2025, increasing the volume of regulated cargo moving through major export terminals.
Ammonium nitrate content thresholds and detonation triggers determine whether an NPK shipment travels as Group B or Group C cargo. Blends exceeding 28 percent ammonium nitrate by mass are Group B and must pass the UN Test Series 5 to prove they do not propagate detonation. The test subjects the fertilizer to a booster charge in a confined steel tube; if the reaction velocity exceeds the threshold, the cargo is prohibited from sea transport. Blends between 0.2 and 28 percent ammonium nitrate are Group C but still require a statement from the manufacturer confirming the cargo is free from combustible contaminants and has been cooled below 35 degrees Celsius before loading. Contamination with chlorides, sulfides, or metal powders lowers the decomposition onset temperature, creating a hidden detonation risk that visual inspection cannot detect.
Toxic gas evolution from NPK cargoes occurs during thermal decomposition or reaction with moisture and acidic hold residues. Ammonium nitrate decomposition releases nitrogen oxides, primarily nitrogen dioxide, which appears as a brown plume and exceeds occupational exposure limits at 5 ppm. Ammonia gas evolves when alkaline cargo dust contacts acidic residues from previous coal or sulphur shipments, reaching concentrations that irritate eyes and respiratory tracts at 25 ppm. Fixed gas detectors mounted at the top of the hold and portable multi-gas meters used during entry must alarm at 25 ppm for ammonia and 1 ppm for nitrogen dioxide. Ventilation must remain sealed during a decomposition event to starve the reaction of oxygen; opening hatches feeds the fire and spreads toxic gas across the deck.
IMSBC Code Group B special requirements for high-AN NPK blends mandate a certificate of compliance, temperature monitoring, and strict stowage segregation. The certificate must state the product name, UN number 2067 or 2071 as applicable, ammonium nitrate percentage, and the result of the UN Test Series 5. During loading, cargo temperature must not exceed 35 degrees Celsius and must be recorded in the ship's log every four hours. High-AN NPK must be stowed away from fuel oil tanks, heated cargo tanks, and engine room bulkheads with a minimum separation of one complete compartment. Electrical equipment in the hold must be certified for dust ignition protection. The master must receive a fire-fighting procedure specific to nitrate fertilizers, emphasizing the prohibition of steam, CO2, or smothering agents that can accelerate decomposition.
Critical Relative Humidity (CRH) values for common NPK blends at 25 degrees Celsius and 30 degrees Celsius dictate the ventilation strategy and the risk of caking during transit. A standard 15-15-15 granular blend has a CRH of approximately 61 percent at 25 degrees Celsius, dropping to 55 percent at 30 degrees Celsius. High-nitrogen blends containing ammonium nitrate exhibit lower CRH values near 55 percent at 25 degrees Celsius, making them hygroscopic in most tropical loading zones. When ambient humidity exceeds the CRH, the fertilizer absorbs moisture until equilibrium is reached, dissolving surface crystals and forming liquid bridges that harden into cakes. By May 2026 the global fertilizer basket averaged $595 per tonne, up $120 from February 2026, raising the commercial stakes of moisture damage claims.
Critical Relative Humidity (CRH) values for common NPK blends at 25 degrees Celsius and 30 degrees Celsius determine the maximum safe hold humidity before moisture uptake begins. Granular 15-15-15 shows a CRH of 61 percent at 25 degrees Celsius and 55 percent at 30 degrees Celsius. Prilled urea-based blends drop to 55 percent at 25 degrees Celsius and 49 percent at 30 degrees Celsius. High-nitrogen AN-based grades fall further to 52 percent at 25 degrees Celsius and 46 percent at 30 degrees Celsius. High-phosphorus SSP-rich blends hold the highest CRH near 70 percent at 25 degrees Celsius. These figures guide the master's decision to ventilate or seal the hold; if outside air humidity exceeds the cargo CRH, ventilation introduces moisture and accelerates caking.
Transportable Moisture Limit (TML) sampling and certification per IMSBC Appendix 2 is mandatory for NPK blends classified as Group A cargoes liable to liquefy. The shipper must provide a certificate stating the TML and the actual moisture content, which must be below the TML. Sampling follows the flow table method: representative samples are taken from the stockpile during loading, sealed in airtight containers, and tested within seven days. If the cargo moisture exceeds the TML at any point, loading must stop until re-testing confirms compliance. The master must verify the certificate date matches the cargo on board and that the moisture content declared is not older than seven days. Failure to present a valid TML certificate is a common Port State Control detention item for fertilizer bulk carriers.
Caking mechanisms in NPK fertilizers begin when moisture uptake exceeds the CRH and dissolved salts form crystal bridges between particles. The threshold for visible caking is typically 0.5 percent above the equilibrium moisture content at the prevailing hold temperature. Anti-caking agents such as magnesium carbonate, talc, or proprietary surfactants coat particles to delay moisture absorption, but their efficacy declines after three to six months of storage or if the cargo is exposed to rain during loading. Once caking initiates, mechanical discharge with grabs breaks the cake into lumps that can damage conveyor belts and create dust explosions in shore silos. Shippers should declare the anti-caking agent type and application date on the cargo information form so the receiver can plan discharge equipment accordingly.
| NPK Blend Type | CRH at 25°C (%) | CRH at 30°C (%) | Equilibrium Moisture at CRH (% wt) | Typical Anti-Caking Agent |
|---|---|---|---|---|
| Standard 15-15-15 granular | 61 | 55 | 0.8 | Magnesium carbonate |
| High Nitrogen (AN based) | 52 | 46 | 1.2 | Talc + surfactant |
| High Phosphorus (SSP rich) | 70 | 64 | 0.5 | None typically |
| Prilled urea blend | 55 | 49 | 1.0 | Proprietary surfactant |
The table compares critical relative humidity and equilibrium moisture for four common NPK blend types. High-nitrogen ammonium nitrate blends show the lowest CRH values, meaning they absorb moisture earliest in humid climates and require the most aggressive ventilation control. Prilled urea blends follow closely, while high-phosphorus SSP-rich grades tolerate higher humidity before caking initiates. Equilibrium moisture content at the CRH indicates the maximum water the cargo can hold without free liquid forming; exceeding this value raises liquefaction risk for Group A cargoes. Anti-caking agent selection correlates with blend chemistry: magnesium carbonate suits granular NPK, while proprietary surfactants are needed for prilled products to maintain flowability during extended voyages.
Pre-loading hold inspection begins with visual confirmation that all loose scale, rust flakes, and previous cargo residues have been removed to a "grain clean" or "hospital clean" standard depending on the charterparty definition. Surveyors verify hold cleanliness using white-glove tests on tank tops and hopper tanks, while chemical residue tests such as pH swabs and chloride checks detect invisible contamination from prior cargoes like coal or sulphur. The master retains the gas-free certificate, the hold cleaning certificate, and photographic evidence of the cleaned holds for presentation to shippers and insurers. Failure to meet these standards triggers rejection at load port and potential off-hire disputes.
High-ammonium nitrate NPK blends classified under IMSBC Code Group B require strict segregation from acid-forming cargoes, sulphur, and carbonaceous materials to prevent sensitisation of the nitrate component. Phosphate-rich grades such as single superphosphate blends generate acidic leachate that corrodes steel and reacts with alkaline residues, demanding thorough freshwater washing after high-pH cargoes like cement or lime. Potash-containing blends are hygroscopic but chemically stable; however, they must not be stowed adjacent to wet cargoes that could migrate moisture through bulkheads. The compatibility matrix below summarises key segregation rules for common NPK blend families to prevent cross-contamination and chemical interaction during mixed-grade voyages.
| NPK Blend Family | IMSBC Group | Prohibited Adjacent Cargoes | Required Bulkhead Condition | Cleaning Priority After |
|---|---|---|---|---|
| High Nitrogen (AN based) | Group B | Sulphur, carbon, acids, chlorates | Gas-tight, coated | Coal, sulphur, petcoke |
| Standard Granular NPK | Group C | Wet cargoes, strong acids | Structurally sound | Cement, lime, fertiliser dust |
| High Phosphorus (SSP rich) | Group C | Alkaline residues, ammonia | Acid-resistant coating | Cement, clinker, soda ash |
| Prilled Urea Blend | Group C | Nitrates, strong oxidisers, moisture | Gas-tight, dry | Ammonium nitrate, wet cargoes |
The table highlights that high-nitrogen ammonium nitrate blends demand the most rigorous segregation, requiring gas-tight bulkheads and prohibition against sulphur or carbonaceous materials. Standard granular NPK tolerates standard structural bulkheads but remains sensitive to moisture migration from adjacent wet cargoes. High-phosphorus SSP-rich grades require acid-resistant coatings due to low-pH leachate potential, while prilled urea blends must be isolated from nitrate oxidisers and moisture sources. Cleaning priority escalates after cargoes leaving reactive residues such as coal dust or alkaline cement fines.
Charterparty clauses define "clean hold" standards ranging from "shovel clean" for compatible fertiliser-to-fertiliser sequences to "hospital clean" for food-grade or sensitive NPK blends requiring zero contamination risk. Cost allocation for hold cleaning typically falls on the charterer when the previous cargo was nominated by them, while the owner bears costs for routine maintenance cleaning between ballast legs. Lighterage terms specify whether the vessel must gear up for grab discharge or if shore cranes are provided, directly influencing hold protection requirements such as tank top plating thickness and hatch coaming strength. Demurrage clauses often exclude time lost due to hold cleaning delays if the vessel presented holds below the agreed standard at the load port. Clear definitions in the charterparty prevent disputes over cleaning standards, cost recovery, and laytime commencement for NPK bulk shipments.
Structural stress distribution governs hold loading sequences to keep shear forces and bending moments within the vessel's approved loading manual limits. NPK fertiliser bulk densities typically range from 0.9 to 1.3 tonnes per cubic metre, creating high point loads on tank tops and hopper knuckles when poured from height. Planners alternate heavy and light holds in block-loading patterns to minimise hogging and sagging moments, especially on part cargoes where empty holds create stress concentrations. The loading instrument calculates real-time still water shear force and bending moment at each pour, requiring master approval before sequence changes. Double-bottom tanks may be ballasted to reduce tank top pressure in heavily loaded holds, while wing tanks are managed to control torsional stress on wide-beam bulk carriers carrying high-density NPK grades.
Intact stability criteria require the vessel to meet minimum GM values after loading, accounting for the free surface effect of slack ballast tanks and the potential cargo shift angle for NPK blends with angles of repose between 30 and 38 degrees. The cargo securing manual mandates trimming the cargo surface to reduce the heeling moment from a transverse shift, typically requiring a level surface or a slight peak at the centreline. For high-nitrogen AN blends prone to caking, the master must assume a reduced angle of repose in stability calculations if crust formation is observed during loading. GZ curves are verified for the departure, arrival, and intermediate conditions, ensuring the area under the curve exceeds regulatory minimums even with a 15-degree cargo shift assumption for Group B cargoes.
Hold loading sequences for mixed NPK grades prioritise segregation compatibility and stress management simultaneously. High-density AN-based blends are loaded in centre holds to minimise hull bending, while lower-density phosphate or potash grades fill wing holds to balance the transverse centre of gravity. Part cargoes require careful ballast distribution to maintain propeller immersion and forward draft for steering, often necessitating partial fills in multiple holds rather than full holds left empty. The loading sequence avoids pouring high-dust prilled urea blends after granular grades to prevent dust contamination of the lower-stowed cargo. Each pour is documented in the cargo log with hold number, tonnage, blend type, and observed moisture condition for arrival certification and claims defence.
Cargo sweat occurs when warm moist air contacts a cargo surface colder than the air dew point causing condensation on the fertilizer surface. Ship sweat forms when the steel structure is colder than the dew point of the hold atmosphere leading to condensation on bulkheads and frames. The critical differential is the cargo temperature versus the ambient air dew point. If cargo temperature is below the outside air dew point ventilation introduces moisture and cargo sweat risk. If cargo temperature exceeds the outside air dew point ventilation removes moisture and prevents ship sweat. A three degree Celsius margin is the standard safety buffer applied before opening hatches.
The decision matrix compares cargo temperature at three depths with ambient air dew point and hold atmosphere dew point. Ventilation is authorised only when cargo temperature exceeds ambient dew point by at least three degrees and hold dew point exceeds ambient dew point. Sealing is mandatory when cargo temperature is below ambient dew point or when gas monitoring detects ammonia or nitrogen oxides above threshold limits. The matrix is recalculated every watch during temperature profiling. A typical voyage log records the decision at 0400 1200 and 2000 hours with the responsible officer signature.
| Condition | Cargo Temp vs Ambient Dew Point | Hold Dew Point vs Ambient Dew Point | Gas Reading (NH3/NOx) | Action | Log Interval |
|---|---|---|---|---|---|
| Ventilate | Cargo > Ambient DP + 3°C | Hold > Ambient DP | Below TLV | Open hatches run forced draft | Every 4 hours |
| Seal | Cargo < Ambient DP | Any | Any | Close hatches stop fans | Every 4 hours |
| Seal | Any | Any | Above TLV | Close hatches inert if fitted | Continuous |
| Natural | Cargo > Ambient DP + 1°C | Hold < Ambient DP | Below TLV | Open vents no fans | Every 6 hours |
The table reads as a traffic light system. Green rows permit ventilation with forced draft. Red rows mandate sealing and gas monitoring escalation. Amber rows allow natural ventilation only. The cargo temperature is the controlling variable because NPK blends have critical relative humidity points as low as fifty five percent at thirty degrees Celsius. Once the hold is sealed the atmosphere is monitored for oxygen depletion and toxic gas accumulation until discharge.
Gas monitoring protocols require calibrated detectors for ammonia and nitrogen oxides at each hold access point. Ammonia threshold limit value is twenty five parts per million time weighted average. Nitrogen dioxide threshold limit value is three parts per million. Readings are taken before each ventilation decision and recorded in the cargo ventilation log with time position cargo temperature and dew points. If ammonia exceeds fifty parts per million or nitrogen dioxide exceeds five parts per million ventilation stops immediately and the master considers inerting. The log serves as primary evidence for cargo condition claims and port state control inspections.
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Safe NPK bulk transport hinges on recognizing that every blend behaves differently under moisture stress thermal cycling and mechanical load. Stowage plans must reflect the actual angle of repose stowage factor and critical relative humidity of the specific cargo not generic textbook values. Hold preparation cleaning verification and segregation certificates form the documentary backbone that protects owners from contamination claims. Ventilation decisions driven by dew-point differentials not calendar dates preserve cargo quality and prevent hold sweat damage. Voyage temperature profiling gas monitoring and emergency drill records demonstrate due diligence to port state control and underwriters alike. Commercial contracts should embed demurrage clauses that account for NPK-specific discharge delays caused by caking or gas clearance. When charterers shippers and terminals share the same material safety data sheet and emergency schedule the supply chain moves faster with fewer disputes. For verified counterparties and up-to-date trade lanes Global Trade Plaza provides a starting point to connect with vetted fertilizer buyers and sellers.
NPK bulk cargo moves as solid granules loaded directly into ship holds under the IMSBC Code, classified as Group B or C based on ammonium nitrate content and trough test results. The shipper provides a declaration and certificate confirming the group, moisture content, and transportable moisture limit before loading begins. Vessels follow specific ventilation, gas monitoring, and stowage plans assigned to the cargo group for the voyage.
Bulk NPK prices are negotiated per metric tonne on a CFR or FOB basis and fluctuate daily with nitrogen, phosphate, and potash feedstock markets, freight rates, and seasonal demand. There is no fixed public price list; buyers request quotes from suppliers or traders specifying grade, volume, discharge port, and laycan window. Global Trade Plaza lists verified suppliers who publish indicative offers for specific NPK formulations.
A standard pallet of bagged NPK fertilizer typically weighs 1,000 kg (one metric tonne) configured as 40 bags of 25 kg each, though 50 kg bags on 1.25 tonne pallets are common in some regions. Weight varies with bag count and packaging specification, so the bill of lading and packing list must state the exact net weight per pallet. This applies to packaged cargo under IMDG rules, not loose bulk shipments.
Bulk fertilizer is purchased directly from producers, international trading houses, or specialized brokers who charter vessels for full or part cargoes. Buyers also use B2B marketplaces such as Global Trade Plaza to identify verified suppliers, compare offers, and initiate RFQs for specific grades and delivery terms. Government tenders, industry trade shows, and chamber of commerce directories provide additional sourcing channels.
Costco does not sell NPK fertilizer in bulk cargo quantities; it retails bagged lawn and garden products in consumer pack sizes through warehouses and online. Commercial buyers requiring vessel loads must source from wholesale distributors, importers, or directly from manufacturers and traders. Costco is not a channel for IMSBC-regulated bulk commodity transactions.
The stowage factor of NPK fertilizer ranges from 0.95 to 1.15 cubic metres per tonne depending on grade, granule size, and moisture content. High-nitrogen dense blends stow near 0.95 m³/t, standard 15-15-15 granular grades near 1.05 m³/t, and prilled fines-rich blends near 1.15 m³/t. Load planners must use the shipper's declared value to calculate hold capacity and avoid exceeding tank top limits.
The angle of repose for NPK bulk cargo generally falls between 30 and 38 degrees, varying with particle size distribution and moisture level. Fines-rich prilled blends sit at the lower end near 30 degrees, increasing flowability and shift risk, while coarse granular grades maintain steeper cones up to 38 degrees. IMSBC Code requires trimming when the angle exceeds 35 degrees or holds are partially filled.
NPK fertilizer is classified under the IMSBC Code as Group B (UN 2067) when ammonium nitrate content exceeds 28 percent or the trough test shows decomposition propagation, requiring mechanical ventilation and continuous gas monitoring. Group C (UN 2071) applies to blends below the ammonium nitrate threshold that pass the trough test, allowing natural ventilation and periodic checks. The shipper's declaration and manufacturer certificate must confirm the assigned group before loading.
The Transportable Moisture Limit (TML) for NPK fertilizer is the maximum moisture content safe for carriage, determined by the flow table test or penetration test per IMSBC Appendix 2. A valid TML certificate is mandatory for Group A cargoes and recommended for Group B and C to prevent liquefaction risk. Sampling must occur within seven days of loading, and the actual moisture content must remain below the TML throughout the voyage.
Group B NPK cargoes require mechanical ventilation operating continuously throughout the voyage with airflow directed across the cargo surface to disperse toxic gases. Group C cargoes typically use natural ventilation via open hatches or cowls, but ventilation must stop when ambient humidity exceeds the cargo's Critical Relative Humidity to prevent caking. Gas detectors for oxygen, nitrogen dioxide, and ammonia must be active during hold entry.
For Group B NPK fires, the primary action is flooding the hold with copious amounts of water to cool the cargo and prevent detonation; do not use steam, CO2, or foam as they can worsen decomposition. Crew must evacuate adjacent spaces, monitor for brown nitrogen dioxide plumes indicating toxic decomposition, and maintain boundary cooling on bulkheads. The vessel should proceed to the nearest port of refuge while maintaining water application.
Caking is prevented by loading cargo below its Critical Relative Humidity (CRH), which ranges from 46 percent for high-nitrogen blends at 30°C to 70 percent for high-phosphorus grades. Ventilation must cease when outside air humidity exceeds the cargo CRH to avoid moisture absorption. Cargo should be cooled below 35°C before loading, holds must be dry and free of acidic residues, and anti-caking agent treatment should be verified on the manufacturer certificate.